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• W2951439899 abstract "A series of chiral aminophosphine phosphinites DPAMPPs was synthesized from optically active 1,2-diphenyl-2-aminoethanols. The erythro-DPAMPPs were found to serve as excellent ligands for rhodium-catalyzed asymmetric hydrogenation of dehydroamino acid derivatives. For an array of dehydroamino acid precursors, remarkably high enantioselectivity (up to 98.4% e.e.) and reactivity (the ratio of substrate/catalyst up to 10000) were observed. Some factors controlling the enantioselectivity were examined and discussed." @default.
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• W2951439899 date "2000-08-01" @default.
• W2951439899 modified "2023-10-06" @default.
• W2951439899 title "Aminophosphine Phosphinites Derived from Chiral 1,2-Diphenyl-2-aminoethanols: Synthesis and Application in Rhodium-Catalyzed Asymmetric Hydrogenation of Dehydroamino Acid Derivatives" @default.
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• W2951439899 doi "https://doi.org/10.1016/s0040-4020(00)00481-6" @default.
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