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• W2951444145 abstract "Abstract An organic–inorganic hybrid 1D helical chain arsenomolybdate {[Cu(en) 2 ][Cu(en)(H 2 O)][(Cu(en) 2 (H 2 O)] [As III As V Mo 9 O 34 )]} · 2H 2 O ( 1 ) (en = ethylenediamine) has been hydrothermally synthesized and characterized by elemental analyses, IR, UV and CD spectrum, powder X-ray diffraction, TG-DTA and single-crystal X-ray diffraction. The asymmetric unit of 1 consists of a monocapped trivacant Keggin [As III As V Mo 9 O 34 ] 6 − subunit, a pendant [Cu(en) 2 (H 2 O)] 2 + cation, a pendant [Cu(en)(H 2 O)] 2 + cation, one bridging [Cu(en) 2 ] 2 + cation and two lattice water molecules. It should be noted that 1 illustrates a one-dimensional (1D) helical chain assembled by {[Cu(en)(H 2 O)][(Cu(en) 2 (H 2 O)][As III As V Mo 9 O 34 )]} 2 − clusters and [Cu(en) 2 ] 2 + linkers." @default.
• W2951444145 created "2019-06-27" @default.
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• W2951444145 date "2013-02-01" @default.
• W2951444145 modified "2023-09-27" @default.
• W2951444145 title "Synthesis, structural characterization and properties of a novel 1D helical chain arsenomolybdate {[Cu(en)2][Cu(en)(H2O)][(Cu(en)2(H2O)] [AsIIIAsVMo9O34)]}·2H2O" @default.
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• W2951444145 doi "https://doi.org/10.1016/j.inoche.2012.11.004" @default.
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