FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2951445820> ?p ?o ?g. }

• W2951445820 endingPage "5687" @default.
• W2951445820 startingPage "5681" @default.
• W2951445820 abstract "Solution structures of hydridorhodium diphosphite dicarbonyl complexes [HRhL⌒L1-9(CO)2] have been studied. Diphosphites L⌒L1 to L⌒L9 are based on C2 symmetric (2R,3R)-butane-2,3-diol, (2R,3R)-diethyl tartrate, (2R,4R)-pentane-2,4-diol, and (2S,5S)-hexane-2,5-diol backbones substituted with 1,1‘-biphenyl-2,2-diyl- or (S)-(−)-1,1‘-binaphthyl-2,2‘-diylphosphoroxy derivatives. Variable-temperature (293−163 K) 31P and 1H NMR spectroscopy revealed fluxional behavior in the trigonal bipyramidal HRhL⌒L(CO)2 complexes of L⌒L1-9 which could be frozen out at low temperatures. Depending on the length of the bridge between the two phosphorus atoms in the diphosphite ligands, equatorial−axial or bis-equatorial coordination takes place. Enthalpies of activation (ΔH⧧) varying between 36.7 and 62.5 kJ mol-1 have been calculated for the phosphorus exchange observed in these hydridorhodium diphosphite dicarbonyl complexes. The enthalpies of activation increase with larger steric bulkiness of the coordinated diphosphite ligands." @default.
• W2951445820 created "2019-06-27" @default.
• W2951445820 creator A5005138503 @default.
• W2951445820 creator A5005149482 @default.
• W2951445820 creator A5070975248 @default.
• W2951445820 creator A5089678850 @default.
• W2951445820 date "1997-12-01" @default.
• W2951445820 modified "2023-10-13" @default.
• W2951445820 title "Fluxional Processes in Asymmetric Hydroformylation Catalysts [HRhL⌒L(CO)₂] Containing <i>C</i>₂-Symmetric Diphosphite Ligands" @default.
• W2951445820 cites W1964103856 @default.
• W2951445820 cites W1979485094 @default.
• W2951445820 cites W1985684677 @default.
• W2951445820 cites W1989549118 @default.
• W2951445820 cites W2000427955 @default.
• W2951445820 cites W2001385493 @default.
• W2951445820 cites W2010676355 @default.
• W2951445820 cites W2031083940 @default.
• W2951445820 cites W2039334531 @default.
• W2951445820 cites W2040390402 @default.
• W2951445820 cites W2045018605 @default.
• W2951445820 cites W2045449862 @default.
• W2951445820 cites W2045783796 @default.
• W2951445820 cites W2050221163 @default.
• W2951445820 cites W2063589252 @default.
• W2951445820 cites W2077241604 @default.
• W2951445820 cites W2078227271 @default.
• W2951445820 cites W2081404553 @default.
• W2951445820 cites W2091117905 @default.
• W2951445820 cites W2095876113 @default.
• W2951445820 cites W2098463731 @default.
• W2951445820 cites W2102632798 @default.
• W2951445820 cites W2129534167 @default.
• W2951445820 cites W2952175498 @default.
• W2951445820 cites W2952763185 @default.
• W2951445820 cites W3004499543 @default.
• W2951445820 doi "https://doi.org/10.1021/om970599k" @default.
• W2951445820 hasPublicationYear "1997" @default.
• W2951445820 type Work @default.
• W2951445820 sameAs 2951445820 @default.
• W2951445820 citedByCount "83" @default.
• W2951445820 countsByYear W29514458202012 @default.
• W2951445820 countsByYear W29514458202013 @default.
• W2951445820 countsByYear W29514458202014 @default.
• W2951445820 countsByYear W29514458202015 @default.
• W2951445820 countsByYear W29514458202017 @default.
• W2951445820 countsByYear W29514458202018 @default.
• W2951445820 countsByYear W29514458202019 @default.
• W2951445820 countsByYear W29514458202020 @default.
• W2951445820 countsByYear W29514458202021 @default.
• W2951445820 countsByYear W29514458202022 @default.
• W2951445820 countsByYear W29514458202023 @default.
• W2951445820 crossrefType "journal-article" @default.
• W2951445820 hasAuthorship W2951445820A5005138503 @default.
• W2951445820 hasAuthorship W2951445820A5005149482 @default.
• W2951445820 hasAuthorship W2951445820A5070975248 @default.
• W2951445820 hasAuthorship W2951445820A5089678850 @default.
• W2951445820 hasConcept C100805817 @default.
• W2951445820 hasConcept C111592845 @default.
• W2951445820 hasConcept C115624301 @default.
• W2951445820 hasConcept C144002745 @default.
• W2951445820 hasConcept C155647269 @default.
• W2951445820 hasConcept C161790260 @default.
• W2951445820 hasConcept C178516000 @default.
• W2951445820 hasConcept C178790620 @default.
• W2951445820 hasConcept C185592680 @default.
• W2951445820 hasConcept C188027245 @default.
• W2951445820 hasConcept C201194858 @default.
• W2951445820 hasConcept C2777589835 @default.
• W2951445820 hasConcept C2778717364 @default.
• W2951445820 hasConcept C2779515768 @default.
• W2951445820 hasConcept C521398313 @default.
• W2951445820 hasConcept C66974803 @default.
• W2951445820 hasConcept C71240020 @default.
• W2951445820 hasConcept C8010536 @default.
• W2951445820 hasConceptScore W2951445820C100805817 @default.
• W2951445820 hasConceptScore W2951445820C111592845 @default.
• W2951445820 hasConceptScore W2951445820C115624301 @default.
• W2951445820 hasConceptScore W2951445820C144002745 @default.
• W2951445820 hasConceptScore W2951445820C155647269 @default.
• W2951445820 hasConceptScore W2951445820C161790260 @default.
• W2951445820 hasConceptScore W2951445820C178516000 @default.
• W2951445820 hasConceptScore W2951445820C178790620 @default.
• W2951445820 hasConceptScore W2951445820C185592680 @default.
• W2951445820 hasConceptScore W2951445820C188027245 @default.
• W2951445820 hasConceptScore W2951445820C201194858 @default.
• W2951445820 hasConceptScore W2951445820C2777589835 @default.
• W2951445820 hasConceptScore W2951445820C2778717364 @default.
• W2951445820 hasConceptScore W2951445820C2779515768 @default.
• W2951445820 hasConceptScore W2951445820C521398313 @default.
• W2951445820 hasConceptScore W2951445820C66974803 @default.
• W2951445820 hasConceptScore W2951445820C71240020 @default.
• W2951445820 hasConceptScore W2951445820C8010536 @default.
• W2951445820 hasIssue "26" @default.
• W2951445820 hasLocation W29514458201 @default.
• W2951445820 hasOpenAccess W2951445820 @default.
• W2951445820 hasPrimaryLocation W29514458201 @default.
• W2951445820 hasRelatedWork W1972429726 @default.
• W2951445820 hasRelatedWork W2059870480 @default.

• next