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- W2951448905 abstract "Several complexes of the type RuTp(L)(L′)Cl (L, L′=P, N, O donors) were tested with respect to their ability of promoting catalytic C–C-coupling reactions of terminal acetylenes. When L=tertiary phosphine, predominantly dimerization occurs, RuTp(PPh3)2H being the most efficient pre-catalyst. In the absence of a phosphine ligand, polymerization takes place with RuTp(COD)Cl as the most effective pre-catalyst. Both product distribution and conversion depend strongly on the substituent of the alkyne and to a lesser extent on the co-ligands of the ruthenium complex. The catalytically active species is the 16e− alkynyl complex RuTp(L)(–C*C–R) which in case of L=PCy 3 and R=Bu n could be trapped as RuTp(PCy3)(–C*CBu n )(CO)." @default.
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- W2951448905 date "2010-06-21" @default.
- W2951448905 modified "2023-09-26" @default.
- W2951448905 title "ChemInform Abstract: Ruthenium Catalyzed Homocoupling of Terminal Alkynes." @default.
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- W2951448905 doi "https://doi.org/10.1002/chin.199827048" @default.
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