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- W2951451566 abstract "Measurements of H2 evolution revealed that neither 5-trifluoroacetamido-1-pentanol (1) nor 5-acetamido-1-pentanol (6) underwent complete bisdeprotonation upon treatment with excess NaH in THF, thereby accounting for the unexpected course of subsequent alkylations with carbohydrate-derived triflates 2 and 7. These studies in turn led to an effective protocol for generation of N,O-dianions from 1 and 6; as anticipated, the former chemoselectively furnished O-alkylation products with triflates 2 and 15." @default.
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- W2951451566 date "1995-04-01" @default.
- W2951451566 modified "2023-10-18" @default.
- W2951451566 title "Chemoselective monoalkylation of 5-trifluoroacetamido- and 5-acetamido-1-pentanol derivatives via N,O-bisdeprotonation. Quantitation of evolved H2 as a probe of anion formation" @default.
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- W2951451566 doi "https://doi.org/10.1016/0040-4039(95)00280-p" @default.
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