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- W2951453591 abstract "A new strategy has been established for the kinetic resolution of racemic allylic alcohols through a palladium/sulfonyl-hydrazide-catalyzed asymmetric OH-substitution under mild conditions. In the presence of 1 mol % [Pd(allyl)Cl]2 , 4 mol % (S)-SegPhos, and 10 mol % 2,5-dichlorobenzenesulfonyl hydrazide, a range of racemic allylic alcohols were smoothly resolved with selectivity factors of more than 400 through an asymmetric allylic alkylation of monosubstituted hydrazines under air at room temperature. Importantly, this kinetic resolution process provided various allylic alcohols and allylic hydrazine derivatives with high enantiopurity." @default.
- W2951453591 created "2019-06-27" @default.
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- W2951453591 date "2016-11-01" @default.
- W2951453591 modified "2023-09-22" @default.
- W2951453591 title "ChemInform Abstract: Kinetic Resolution of Racemic Allylic Alcohols by Catalytic Asymmetric Substitution of the OH Group with Monosubstituted Hydrazines." @default.
- W2951453591 cites W2475110229 @default.
- W2951453591 doi "https://doi.org/10.1002/chin.201648062" @default.
- W2951453591 hasPublicationYear "2016" @default.
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