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- W2951454301 abstract "A new enantioselective synthetic method for α-halo-α-alkylmalonates is reported. α-Alkylation of diphenylmethyl tert-butyl α-halomalonates under phase-transfer catalytic conditions (solid KOH, toluene, −40 °C) in the presence of (S,S)-3,4,5-trifluorophenyl-NAS bromide (5 mol%) afforded diphenylmethyl tert-butyl α-halo-α-alkylmalonates in very high chemical yields (up to 99%) and optical yields (up to 93% ee)." @default.
- W2951454301 created "2019-06-27" @default.
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- W2951454301 date "2014-06-12" @default.
- W2951454301 modified "2023-09-27" @default.
- W2951454301 title "ChemInform Abstract: Enantioselective Synthesis of α-Halo-α-alkylmalonates via Phase-Transfer Catalytic α-Alkylation." @default.
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- W2951454301 doi "https://doi.org/10.1002/chin.201426060" @default.
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