Matches in SemOpenAlex for { <https://semopenalex.org/work/W2951464968> ?p ?o ?g. }
Showing items 1 to 95 of
95
with 100 items per page.
- W2951464968 abstract "The crystal structure of the title compound has been determined from three-dimensional X-ray diffraction data. The compound crystallises in space group P21 with a= 12.073(6), b= 15.824(7), c= 10.162(5)A, β= 100.3(1)°, and Z= 2. The structure was solved by Patterson and Fourier methods; full-matrix least-squares refinement based on 1 836 observed reflections gave a final R value of 0.054 (R′= 0.048). There is a distorted octahedral array of ligands around the uranium atom with the triphenylphosphine oxide (tppo) molecules co-ordinated in trans positions. The U–O distances are 2.21(3) and 2.24(2)A, and the U–Br distances range from 2.758(5) to 2.800(5)A. A new crystal modification of tetrachlorobis(triphenylphosphine oxide)uranium (IV), β-UCl4·2tppo, is reported. The structural data are discussed in conjunction with i.r. results for this metastable phase, for α-UCl4·2tppo, and for other actinide complexes of the type MX4·2tppo (M = Th–Pu inclusive; X = Cl or Br). It is concluded that the β-phase is the trans isomer. Solid-state electronic spectra are reported for α- and β-UCl4·2tppo and UBr4·2tppo." @default.
- W2951464968 created "2019-06-27" @default.
- W2951464968 creator A5003510419 @default.
- W2951464968 creator A5038568587 @default.
- W2951464968 creator A5059551658 @default.
- W2951464968 creator A5061234792 @default.
- W2951464968 creator A5068080128 @default.
- W2951464968 date "1983-05-17" @default.
- W2951464968 modified "2023-09-27" @default.
- W2951464968 title "ChemInform Abstract: TRIPHENYLPHOSPHINE OXIDE COMPLEXES OF ACTINIDE TETRAHALIDES. CRYSTAL AND MOLECULAR STRUCTURE OF TRANS-TETRABROMOBIS(TRIPHENYLPHOSPHINE OXIDE)URANIUM(IV)" @default.
- W2951464968 cites W1978646094 @default.
- W2951464968 doi "https://doi.org/10.1002/chin.198320276" @default.
- W2951464968 hasPublicationYear "1983" @default.
- W2951464968 type Work @default.
- W2951464968 sameAs 2951464968 @default.
- W2951464968 citedByCount "0" @default.
- W2951464968 crossrefType "journal-article" @default.
- W2951464968 hasAuthorship W2951464968A5003510419 @default.
- W2951464968 hasAuthorship W2951464968A5038568587 @default.
- W2951464968 hasAuthorship W2951464968A5059551658 @default.
- W2951464968 hasAuthorship W2951464968A5061234792 @default.
- W2951464968 hasAuthorship W2951464968A5068080128 @default.
- W2951464968 hasConcept C115624301 @default.
- W2951464968 hasConcept C135788738 @default.
- W2951464968 hasConcept C147789679 @default.
- W2951464968 hasConcept C149635348 @default.
- W2951464968 hasConcept C161790260 @default.
- W2951464968 hasConcept C178790620 @default.
- W2951464968 hasConcept C179104552 @default.
- W2951464968 hasConcept C185592680 @default.
- W2951464968 hasConcept C191897082 @default.
- W2951464968 hasConcept C192562407 @default.
- W2951464968 hasConcept C198819137 @default.
- W2951464968 hasConcept C199360897 @default.
- W2951464968 hasConcept C2777247709 @default.
- W2951464968 hasConcept C2779198548 @default.
- W2951464968 hasConcept C2779851234 @default.
- W2951464968 hasConcept C2780049914 @default.
- W2951464968 hasConcept C2781285689 @default.
- W2951464968 hasConcept C32909587 @default.
- W2951464968 hasConcept C41008148 @default.
- W2951464968 hasConcept C555451288 @default.
- W2951464968 hasConcept C58312451 @default.
- W2951464968 hasConcept C8010536 @default.
- W2951464968 hasConcept C89464430 @default.
- W2951464968 hasConceptScore W2951464968C115624301 @default.
- W2951464968 hasConceptScore W2951464968C135788738 @default.
- W2951464968 hasConceptScore W2951464968C147789679 @default.
- W2951464968 hasConceptScore W2951464968C149635348 @default.
- W2951464968 hasConceptScore W2951464968C161790260 @default.
- W2951464968 hasConceptScore W2951464968C178790620 @default.
- W2951464968 hasConceptScore W2951464968C179104552 @default.
- W2951464968 hasConceptScore W2951464968C185592680 @default.
- W2951464968 hasConceptScore W2951464968C191897082 @default.
- W2951464968 hasConceptScore W2951464968C192562407 @default.
- W2951464968 hasConceptScore W2951464968C198819137 @default.
- W2951464968 hasConceptScore W2951464968C199360897 @default.
- W2951464968 hasConceptScore W2951464968C2777247709 @default.
- W2951464968 hasConceptScore W2951464968C2779198548 @default.
- W2951464968 hasConceptScore W2951464968C2779851234 @default.
- W2951464968 hasConceptScore W2951464968C2780049914 @default.
- W2951464968 hasConceptScore W2951464968C2781285689 @default.
- W2951464968 hasConceptScore W2951464968C32909587 @default.
- W2951464968 hasConceptScore W2951464968C41008148 @default.
- W2951464968 hasConceptScore W2951464968C555451288 @default.
- W2951464968 hasConceptScore W2951464968C58312451 @default.
- W2951464968 hasConceptScore W2951464968C8010536 @default.
- W2951464968 hasConceptScore W2951464968C89464430 @default.
- W2951464968 hasLocation W29514649681 @default.
- W2951464968 hasOpenAccess W2951464968 @default.
- W2951464968 hasPrimaryLocation W29514649681 @default.
- W2951464968 hasRelatedWork W1587212544 @default.
- W2951464968 hasRelatedWork W1973078630 @default.
- W2951464968 hasRelatedWork W1978646094 @default.
- W2951464968 hasRelatedWork W2015222324 @default.
- W2951464968 hasRelatedWork W2044243960 @default.
- W2951464968 hasRelatedWork W2059774312 @default.
- W2951464968 hasRelatedWork W2059991875 @default.
- W2951464968 hasRelatedWork W2069545279 @default.
- W2951464968 hasRelatedWork W2076958543 @default.
- W2951464968 hasRelatedWork W2078711592 @default.
- W2951464968 hasRelatedWork W2085543887 @default.
- W2951464968 hasRelatedWork W2086078058 @default.
- W2951464968 hasRelatedWork W2087519575 @default.
- W2951464968 hasRelatedWork W2093763158 @default.
- W2951464968 hasRelatedWork W2112052671 @default.
- W2951464968 hasRelatedWork W2124473700 @default.
- W2951464968 hasRelatedWork W2164093335 @default.
- W2951464968 hasRelatedWork W2949212173 @default.
- W2951464968 hasRelatedWork W2950060439 @default.
- W2951464968 hasRelatedWork W2953379063 @default.
- W2951464968 isParatext "false" @default.
- W2951464968 isRetracted "false" @default.
- W2951464968 magId "2951464968" @default.
- W2951464968 workType "article" @default.