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• W2951468110 abstract "Synthesis and crystal structure of a new compound, BaCuZn(3)As(3), are reported. Single crystals of BaCuZn(3)As(3) are synthesized via NaCl/KCl flux reaction in a sealed fused silica ampule. Its elemental composition has been determined to be Ba/Cu/Zn/As = 1.03(4):1(0):2.91(6):2.98(3), suggesting BaCuZn(3)As(3) as the chemical formula. The structure of BaCuZn(3)As(3) has been determined by X-ray diffraction. It crystallizes in the orthorhombic Cmcm space group with a = 4.2277(3) A, b = 12.970(1) A, and c = 12.011(1) A at T = 90.7 K, and it exhibits a columnar structure along the a-axis. This structure is isotypic to beta-BaCu(4)S(3) but highly distorted. beta-BaCu(4)S(3) is considered to be a layered structure whereas BaCuZn(3)As(3) is a three-dimensional network." @default.
• W2951468110 created "2019-06-27" @default.
• W2951468110 creator A5040142125 @default.
• W2951468110 creator A5056081806 @default.
• W2951468110 date "2003-04-18" @default.
• W2951468110 modified "2023-10-18" @default.
• W2951468110 title "NaCl/KCl Flux Single Crystal Growth and Crystal Structure of the New Quaternary Mixed-Metal Pnictide: BaCuZn₃As₃" @default.
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• W2951468110 doi "https://doi.org/10.1021/ic034061k" @default.
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