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- W2951473896 abstract "A practical and mild set of conditions for the Sonogashira reaction utilizing CsF-mediated in situ TMS-alkyne desilylation followed by Sonogashira coupling has been developed for the synthesis of a variety of alkynyl benzenes and heteroarenes in good to excellent yields. This methodology demonstrates excellent functional group tolerance and simple purification, which allows large-scale industrial applications. This one-pot protocol enables a high-yielding Sonogashira coupling with volatile alkynes by avoiding challenging isolation of free alkynes." @default.
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- W2951473896 date "2019-06-13" @default.
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- W2951473896 title "CsF-Mediated in Situ Desilylation of TMS-Alkynes for Sonogashira Reaction" @default.
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- W2951473896 doi "https://doi.org/10.1021/acs.joc.9b01307" @default.
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