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- W2951475265 abstract "The unit cell of Na[OCN] has been determined on single crystals at 170 K to have rhombohedral symmetry with the lattice parameters a = 356.79(10) and c = 1512.3(5) pm (hexagonal setting). According to the only model for which a converging refinement could be achieved, Na[OCN] crystallizes isopointal to β -NaN 3 in the space group R¯3m (no. 166, Z = 3) with a statistically disordered [OCN]− anion. The positional coordinates and displacement parameters could not be separated for the O and N end atoms of the triatomic anion. The vibrational spectra show the frequencies typical for an [OCN]− moiety with Fermi resonance between the 2δ and the ν sym vibrations for which the undisturbed frequencies were calculated." @default.
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- W2951475265 date "2010-04-01" @default.
- W2951475265 modified "2023-09-24" @default.
- W2951475265 title "Single-Crystal X-Ray Diffraction Study of Na[OCN] at 170 K and its Vibrational Spectra" @default.
- W2951475265 doi "https://doi.org/10.1515/znb-2010-0416" @default.
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