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- W2951491013 abstract "We study experimentally the current (I)-voltage (V) curves of 1:1, 2:1, 3:1, 2:2, 1:2, and 1:3 electrolytes in positively and negatively charged conically-shaped pores of nanoscale dimensions. The positive charges are poly(allylamine hydrochloride) chains functionalized on the pore surface by electrostatic interactions while the negative charges are carboxylic acid groups. Under physiological conditions, these fixed-charge groups are ionized and strongly interact with the different monovalent, divalent, and trivalent ions in the pore solution. The current rectification of the I-V curves and the membrane potentials provide fundamental information on the interaction of the pore charge groups with the mobile ions present at electrochemically and biologically relevant concentrations. The different pores and electrolytes studied, together with the abundant experimental data provided, can be useful to develop new theoretical simulations of transport phenomena in nanoscale solutions that are confined within charged surfaces." @default.
- W2951491013 created "2019-06-27" @default.
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- W2951491013 date "2019-10-01" @default.
- W2951491013 modified "2023-10-02" @default.
- W2951491013 title "Ionic transport characteristics of negatively and positively charged conical nanopores in 1:1, 2:1, 3:1, 2:2, 1:2, and 1:3 electrolytes" @default.
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- W2951491013 doi "https://doi.org/10.1016/j.jcis.2019.06.061" @default.
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