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- W2951497408 abstract "The preparation of a novel chiral 2,2′-bis(MeO-PEG-supported)-6,6′-bis(diphenylphosphanyl)biphenyl (MeO-PEG-Biphep) ligand is described. The derived ruthenium complex catalyzes the hydrogenation of β-ketoesters in up to 99% yield and 99% ee under atmospheric pressure. The accelerating effects exerted by the PEG linkage are dramatic when compared to the unsupported analogue, MeO-Biphep-RuBr2. Furthermore, the catalyst can be recovered easily and the recycled catalysts were shown to maintain their efficiency in two consecutive runs, albeit with declining activity. One of the products, (S)-ethyl-3-hydroxy-3-phenylpropanoate, is useful in the preparation of (S)-fluoxetine." @default.
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- W2951497408 date "2006-09-01" @default.
- W2951497408 modified "2023-09-26" @default.
- W2951497408 title "Enantioselective Hydrogenation of β-Ketoesters Using a MeO-PEG-Supported Biphep Ligand under Atmospheric Pressure: A Practical Synthesis of (<i>S</i>)-Fluoxetine" @default.
- W2951497408 doi "https://doi.org/10.1055/s-2006-949650" @default.
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