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- W2951502708 abstract "Conjugate addition to 1,4-dicarbonylbut-2-enes will generate an α-stereogenic center with respect to one of the carbonyl groups, which informally, can be considered as an inversion of normal reactivity patterns or umpolung protocol. In this paper, the addition of tert-butyl mercaptan to 1,4-dicarbonylbut-2-enes including (E)-4-oxo-4-arylbutenamides and (E)-4-oxo-4-arylbutenones has been developed, to synthesize a series of chiral sulfur-substituted α-stereogenic amides and ketones in high regioselectivity and enantioselectivity (up to 98% ee)." @default.
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- W2951502708 date "2012-03-01" @default.
- W2951502708 modified "2023-10-13" @default.
- W2951502708 title "ChemInform Abstract: Synthesis of Sulfur-Substituted α-Stereogenic Amides and Ketones: Highly Enantioselective Sulfa-Michael Additions of 1,4-Dicarbonylbut-2-enes." @default.
- W2951502708 cites W1980389716 @default.
- W2951502708 doi "https://doi.org/10.1002/chin.201213047" @default.
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