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- W2951516932 abstract "The ion conductivity of zirconium hydrogen monothiophosphate (Zr(HPO3S)2·1.5H2O) has been measured by impedance spectroscopy. The measured value of proton conductivity is 3 × 10-5 S/cm at 298 K. Conductivity was shown to decrease with increasing temperature due to a dehydration process. Above 450 K, the conductivity is likely governed by proton transport in the anhydrous phase Zr(HPO3S)2. The activation energies of proton conductivity were measured to be 18 ± 2 kJ/mol for Zr(HPO3S)2·1.5H2O and 60 ± 3 kJ/mol for the anhydrous compound. The kinetics of ion exchange was studied with the use of potentiometric titration for several ion pairs, H+/Na+, H+/Zn2+, and Na+/Zn2+ in Zr(HPO3S)2·1.5H2O. The diffusion coefficient values for H+/Na+ ion exchange in Zr(HPO3S)2·1.5H2O are lower than those reported in α-zirconium phosphate. At the same time, the mobility of zinc ions in Zr(HPO3S)2·1.5H2O is higher than sodium ion mobility. The ion exchange H+/Zn2+ is accompanied by the slow hydrolysis of the initial compound. In all cases, the powdered solids were evaluated by powder X-ray diffraction, and particle sizes were controlled by grinding and sieving the powders." @default.
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- W2951516932 date "2004-09-29" @default.
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- W2951516932 title "Cation Mobility and Kinetics of Ion Exchange in Zirconium Hydrogen Monothiophosphate Hydrate, Zr(HPO<sub>3</sub>S)<sub>2</sub>·1.5H<sub>2</sub>O" @default.
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- W2951516932 doi "https://doi.org/10.1021/ic035293m" @default.
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