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- W2951520552 abstract "<i>N</i>-(<i>Z</i>)-(2-Cyano-1-phenylethenyl)imidazole-2-carbothioamides have been synthesized in up to 91% yield by the new reaction between 1-substituted imidazoles and isothiocyanates in the presence of cyanophenylacetylene under catalyst- and solvent-free conditions at room temperature. The reaction proceeds via zwitterion–carbene intermediates which are trapped by isothiocyanates to form the zwitterion with ambident N–S anionic site, which then undergoes stereo- and regioselective migration of the alkenyl moiety." @default.
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- W2951520552 date "2012-08-08" @default.
- W2951520552 modified "2023-10-16" @default.
- W2951520552 title "Stereoselective Metal-Free Reaction of Imidazoles with Isothiocyanates Involving Cyanophenylacetylene: A Shortcut to N-(Z-Alkenyl)imidazole-2-carbothioamides" @default.
- W2951520552 doi "https://doi.org/10.1055/s-0031-1290442" @default.
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