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• W2951532520 abstract "The cyclic silylene 6, a silaazaanthracene derivative, which possesses 14-electrons, has been generated by the reduction of 10,10-dichloro-5-methyl-5,10-dihydrophenazasiline (5) with lithium naphthalenide. Reactions of 6 with 2,3-dimethyl-1,3-butadiene, isoprene, and triethylvinylsilane gave the corresponding silylene-trapping products, 7, 8, and 9, in moderate yield. Pseudoaromatic stabilization of the cyclic silylene 6 was not observed, possibly due to the fact that the three rings are not coplanar." @default.
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• W2951532520 date "2001-02-28" @default.
• W2951532520 modified "2023-09-24" @default.
• W2951532520 title "Generation and Reactivity of a New Heterocyclic Silylene, a Silaazaanthracene" @default.
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• W2951532520 doi "https://doi.org/10.1021/om000576x" @default.
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