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• W2951537501 abstract "The dinuclear manganese compound, [MnIV2(μ-O)3(Me3tacn)2](PF6)2 (1) with Me3tacn = 1,4,7-trimethyl-1,4,7-triazacyclononane, catalyzes a variety of bleaching processes and organic substrate oxidations using hydrogen peroxide as oxidant. Bleaching reactions in aqueous solution include stain bleaching for laundry cleaning, stain and starch removal for machine dishwash cleaning, and wood pulp bleaching. Model substrate conversions indicate that in aqueous and non-aqueous media (1) catalyzes both oxygen and electron-transfer reactions. A wide variety of substrates are efficiently converted in non-aqueous media, like alkenes into epoxides and cis-diols, alkanes into their corresponding alcohols and ketones, alcohols into aldehydes and sulfides into sulfoxides and sulfones. Yield and selectivity of reactions frequently depend on the conditions chosen. Dismutation of H2O2 can be controlled by using the appropriate solvent (e.g. acetone) or applying an additive, like oxalate or ascorbic acid. Addition of trichloroacetic acid 2,6-dichlorobenzoic acid to (1)/H2O2 has been shown to give a selective cis-dihydroxylation versus epoxidation (7:1 ratio)." @default.
• W2951537501 created "2019-06-27" @default.
• W2951537501 creator A5064718125 @default.
• W2951537501 creator A5071582383 @default.
• W2951537501 date "2006-05-01" @default.
• W2951537501 modified "2023-09-26" @default.
• W2951537501 title "Bleach and oxidation catalysis by manganese–1,4,7-triazacylononane complexes and hydrogen peroxide" @default.
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• W2951537501 doi "https://doi.org/10.1016/j.molcata.2006.02.032" @default.
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