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- W2951550107 abstract "Abstract Different synthetic routes are available for the formation of dihalogeno-(organylthio)gallanes. Some of the most important reactions leading to these compounds are reported.1–4 Trivalent compounds of gallium are naturally Lewis acids; moreover, in organylthiogallanes a Lewis-base center exists on the sulfur atom. Therefore these molecules have the possibility of both intermolecular and intramolecular Lewis-acid-base interactions, which in the case of intermolecular interactions lead to Lewis-acid-base adducts. The thus formed adducts can be chains or rings of different sizes. Diiodo(organylthio)gallanes are able to form monomers, dimers, and even trimers of different shapes. These differences in the structure are not only due to the group R on the sulfur atom, because investigations on these compounds in solution (molecular weight determinations, and 1H-n.m.r. spectroscopy) and in the solid state (X-ray-structure determinations) have shown differences in the ring sizes for one and the same molecu..." @default.
- W2951550107 created "2019-06-27" @default.
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- W2951550107 date "1987-03-17" @default.
- W2951550107 modified "2023-09-28" @default.
- W2951550107 title "ChemInform Abstract: Ring Molecules Built from GaS-Units" @default.
- W2951550107 cites W2073698455 @default.
- W2951550107 doi "https://doi.org/10.1002/chin.198711375" @default.
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