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- W2951557079 abstract "By designing a novel chiral ion-pair organocatalyst composed of chiral phosphate and DABCO-derived quaternary ammonium, highly enantioselective 3-exo iodo-cycloetherification of allyl alcohols was achieved using NIS as a halogen source. Based on this reaction, one-pot asymmetric 3-exo iodo-cycloetherification/Wagner–Meerwein rearrangement of allyl alcohols en route to enantioenriched 2-iodomethyl-2-aryl cycloalkanones was subsequently developed. Due to the participation of adjacent iodine, the Wagner–Meerwein rearrangement of 2-iodomethyl-2-aryl epoxide proceeds with unusual retention of stereoconfiguration." @default.
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- W2951557079 date "2016-03-01" @default.
- W2951557079 modified "2023-09-27" @default.
- W2951557079 title "ChemInform Abstract: Chiral Ion-Pair Organocatalyst Promotes Highly Enantioselective 3-Exo Iodo-Cycloetherification of Allyl Alcohols." @default.
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- W2951557079 doi "https://doi.org/10.1002/chin.201612028" @default.
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