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- W2951567197 abstract "Abstract The following mechanism steps were verified for the three-component domino cyclisation affording (pyrrolo)quinazolines from 2-(aminomethyl)aniline, a very reactive oxo compound and “usual” oxo compound. The first step was a rapid reaction of very reactive oxo compound (trifluoropyruvate or hexafluoroacetone) with benzylic amino group to form hemiaminal, but not imine; the second step was the reaction of oxo compound with aromatic amino group to form imine (Schiff base) being in equilibrium with its enamine form; the third step was an intramolecular attack of the hemiaminal carbon by the enamine carbon followed by a new nucleophilic rearrangement to form tetrahydropyrimidine cycle; the forth step was closure of the lactam ring, if ester group was available as in trifluoropyruvate." @default.
- W2951567197 created "2019-06-27" @default.
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- W2951567197 date "2014-01-01" @default.
- W2951567197 modified "2023-10-16" @default.
- W2951567197 title "New nucleophilic rearrangement in the mechanism of the three-component domino cyclisation affording fluoroalkylated (pyrrolo)quinazolines" @default.
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- W2951567197 doi "https://doi.org/10.1016/j.jfluchem.2013.10.017" @default.
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