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- W2951567296 abstract "A direct regio- and diastereoselective synthetic route for valuable tetracyclic compounds that employs intramolecular Diels–Alder reactions between furanyl and electron-deficient cyclopropene groups has been developed. The reaction readily proceeds under mild basic conditions to afford potentially bioactive ring-fused tetracyclic compounds in moderate to high yields with high diastereoselectivities (up to > 20:1). Selective reduction reactions of the Diels–Alder adducts with a Zn/acetic acid system can provide octahydro-1H-cyclohepta[c]furan-1-ones, which can subsequently undergo acyl transfer reactions with aliphatic amines." @default.
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- W2951567296 date "2016-11-01" @default.
- W2951567296 modified "2023-09-27" @default.
- W2951567296 title "ChemInform Abstract: Regio- and Stereoselective Synthesis of Valuable Tetracyclic Compounds by Intramolecular Diels-Alder Reactions Between Furan and Cyclopropene Moieties." @default.
- W2951567296 cites W2465393430 @default.
- W2951567296 doi "https://doi.org/10.1002/chin.201648109" @default.
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