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- W2951567645 abstract "Abstract Copper(I) complexes derived from semicorrins, azasemicorrins and bisoxazolines are efficient catalysts for the enantioselective cyclopropanation of silyl enol ethers with diazoacetates. The resulting cyclopropanes can be converted to γ-ketocarboxylates by acid-induced ring cleavage. In this way methyl (2-oxocyclopentyl)- and (2-oxocyclohexyl)acetates have been prepared with up to 90 and 80% ee, respectively." @default.
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- W2951567645 date "1998-08-01" @default.
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- W2951567645 title "Enantioselective copper-catalyzed cyclopropanation of silyl enol ethers" @default.
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- W2951567645 doi "https://doi.org/10.1016/s0040-4020(98)00499-2" @default.
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