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- W2951569416 abstract "The reaction of bis-(2-pyridylmethyl)cyanocuprate (3) with a variety of α,β-unsaturated carbonyl compounds is reported. It has been found that while the reaction with enone goes through a 1,2-addition path, the outcome ofthe reaction with α,β-unsaturated esters depends on the structure of the electrophile, giving the conjugate addition product with γ-hetero-substituted α,β-unsaturated esters. On the other hand, the reaction of 3 with oxygenated butenolides is stereoselective, affording the 1,4-addition product." @default.
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- W2951569416 date "2003-01-01" @default.
- W2951569416 modified "2023-10-12" @default.
- W2951569416 title "Stereoselective Conjugate Addition of Metallated 2-Methylpyridine to Functionalized α,β-Unsaturated Carbonyl Compounds" @default.
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- W2951569416 doi "https://doi.org/10.3987/com-03-9806" @default.
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