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- W2951570111 abstract "Application of the Hemetsberger reaction to ethyl 4-benzyl-7-formyl-2,3-dihydro-1,4-benzoxazine-2-carboxylate (1) or acetate (2) afforded a mixture of ethyl 2,3,4,6-tetrahydro-[1,4]oxazino[2,3-f]indole-7-carboxylate derivatives 3 or 4 and ethyl 2,3,4,9-tetrahydro[1,4]oxazino[3,2-g]indole-8-carboxylate derivatives 5 or 7, with the “linear” derivatives predominant. Michael addition of tert-butyl acrylate to the indole nitrogen atom of 3, 4 and subsequent electrophilic cyclisation gave access to tetracyclic compounds 24, 25. (© Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002)" @default.
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- W2951570111 date "2002-05-01" @default.
- W2951570111 modified "2023-10-09" @default.
- W2951570111 title "Synthesis and Reactivity of 1,4-Oxazinoindole Derivatives" @default.
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- W2951570111 doi "https://doi.org/10.1002/1099-0690(200205)2002:10<1646::aid-ejoc1646>3.0.co;2-k" @default.
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