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• W2951572148 abstract "Abstract Chiral acylnitroso dienophiles 14 , which were obtained from L ‐proline and from D ‐mandelic acid, reacted with cyclohexa‐1,3‐diene to give the expected diastereoisomers 15 and 16 ( Scheme 2 and Table 1 ). The d.e. values for these Diels ‐ Alder reactions were moderate; they are related to the molecular stiffness of the dienophiles. The absolute configuration of the major cycloadducts was interpreted in terms of HOMO/LUMO interactions, the approach being ‘ endo ’ and the acylintroso dienophiles reacting from their s‐ cis ‐conformation." @default.
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• W2951572148 date "1992-02-05" @default.
• W2951572148 modified "2023-10-17" @default.
• W2951572148 title "AsymmetricDiels-Alder Cycloadditions with Chiral Carbamoyl Dienophiles" @default.
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• W2951572148 doi "https://doi.org/10.1002/hlca.19920750108" @default.
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