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- W2951589405 abstract "The western segment of hygrocins A–B has been synthesized through the coupling of a chiral C5–C13 synthon with the sterically demanding hexasubstituted naphthalenic core. The C5–C13 chiral fragment has been assembled via a stereoselective Johnson orthoester rearrangement of an optically pure allylic alcohol derived from d-glucose. Our studies lay the platform for the determination of the absolute configuration of the unassigned C8-stereocenter of the title compounds in addition to the completion of the total synthesis of the unique ansamacrolides hygrocins A and B." @default.
- W2951589405 created "2019-06-27" @default.
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- W2951589405 date "2014-01-01" @default.
- W2951589405 modified "2023-09-25" @default.
- W2951589405 title "Studies towards the total synthesis of hygrocins A and B" @default.
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- W2951589405 doi "https://doi.org/10.1016/j.tetlet.2013.12.017" @default.
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