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• W2951593061 abstract "Three factors that can direct 6-endo radical cyclization over 5-exo ring closure: substitution at C-5, vinyl radical cyclization and ring strain, have been considered in the context of the preparation of carbapyranoses from carbohydrate derivatives. As a result, alkyl radicals in substrates containing a strain inducing 2,3-O-isopropylidene ring, and vinyl radical in non-strained compounds undergo a completely regioselective 6-endo-trig ring closure leading to carbasugar derivatives." @default.
• W2951593061 created "2019-06-27" @default.
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• W2951593061 date "2007-02-01" @default.
• W2951593061 modified "2023-10-14" @default.
• W2951593061 title "6-endo Versus 5-exo radical cyclization: streamlined syntheses of carbahexopyranoses and derivatives by 6-endo-trig radical cyclization" @default.
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• W2951593061 doi "https://doi.org/10.1016/j.tetlet.2006.12.108" @default.
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