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- W2951595087 abstract "Introduction of a homochiral p-tolylsulfinyl group at an appropriate position in the alkene accelerates the thermal [5C + 2C] intramolecular cycloaddition to beta-silyloxy-gamma-pyrones and, most importantly, leads to excellent levels of diastereodifferentiation. The resulting adducts can be easily desulfinylated to give optically active 8-oxabicyclic[3.2.1]octane intermediates which by virtue of their rich functionalization might be susceptible to elaboration into enantiomerically pure natural products containing seven-membered carbocycles and tetrahydrofurans." @default.
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- W2951595087 date "2000-03-16" @default.
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- W2951595087 title "Sulfinyl-Directed Diastereoselective [5 + 2] Pyrone−Alkene Cycloadditions: A Practical Route to Enantiopure 8-Oxabicyclo[3.2.1]octane Derivatives" @default.
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- W2951595087 doi "https://doi.org/10.1021/ol005724u" @default.
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