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- W2951605341 abstract "The analysis of the proton magnetic resonance spectrum of a 10 mol % solution of 3,5-dichlorobenzyl mercaptan in deuterated benzene yields –0.42 Hz for the spin–spin coupling constant over six bonds between the methylene protons and the ring proton in the para position. A hindered rotor treatment, combined with the assumption of a simple angle dependence of the spin–spin coupling, yields a value of 1.8 ± 0.2 kcal mol–1 for the twofold barrier to rotation about the carbon–carbon bond. The low-energy conformation is that in which the carbon–sulphur bond lies in a plane perpendicular to that of the benzene plane." @default.
- W2951605341 created "2019-06-27" @default.
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- W2951605341 date "1977-12-06" @default.
- W2951605341 modified "2023-09-23" @default.
- W2951605341 title "ChemInform Abstract: NUCLEAR MAGNETIC RESONANCE MEASUREMENT OF THE SMALL BARRIER TO ROTATION ABOUT THE CARBON-CARBON BOND IN 3,5-DICHLOROBENZYL MERCAPTAN" @default.
- W2951605341 cites W2000005338 @default.
- W2951605341 doi "https://doi.org/10.1002/chin.197749069" @default.
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