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• W2951615249 abstract "Tetrabutylammonium hydroxide (TBAH) is an efficient and mild alternative to tetrabutylammonium fluoride (TBAF) for base catalyzed cyclizations of 1,2,4-oxadiazoles from O-acylamidoximes. For most 3,5-substituted 1,2,4-oxadiazoles the reactions were dramatically accelerated by addition of 0.1 equiv of TBAH at room temperature. This method was also more generally applicable allowing for a wider range of substrates. Additionally, due to the absence of fluoride, TBAH will not result in corrosion of reactor vessels and therefore is better suited for large-scale synthesis." @default.
• W2951615249 created "2019-06-27" @default.
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• W2951615249 date "2014-01-01" @default.
• W2951615249 modified "2023-10-18" @default.
• W2951615249 title "Construction of 3,5-substituted 1,2,4-oxadiazole rings triggered by tetrabutylammonium hydroxide: a highly efficient and fluoride-free ring closure reaction of O-acylamidoximes" @default.
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• W2951615249 doi "https://doi.org/10.1016/j.tetlet.2013.12.016" @default.
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