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- W2951617952 abstract "This chapter discusses synthesis and determination of thiosulfate and polythionates. Thiosulfate and polythionates react with cyanide to form thiocyanate, which can be determined colorimetrically as ferric thiocyanate. Differences in the reactivity of the thionates with cyanide enable the quantitative characterization and determination of mixtures of several compounds: trithionate is stable at high pH values and reacts with cyanide only at elevated temperatures, thiosulfate reacts with cyanide at room temperature only in the presence of copper(II) as a catalyst, whereas the higher polythionates react rapidly with cyanide at room temperature to form thiosulfate and sulfite. Thiocyanate formation can be quantified by reference to a calibration curve using thiocyanate or thiosulfate standards. In all the procedures in which ferric thiocyanate is measured, caution needs to be exercised, as the color is light sensitive and readings should be made at once or samples stored in darkness after addition of ferric reagent. The sensitivity of the procedure can be enhanced by using small volumes of more concentrated reagents and reading optical density in long light path (4 cm) cuvettes." @default.
- W2951617952 created "2019-06-27" @default.
- W2951617952 creator A5008205224 @default.
- W2951617952 creator A5047570597 @default.
- W2951617952 date "1994-01-01" @default.
- W2951617952 modified "2023-10-12" @default.
- W2951617952 title "[35] Synthesis and determination of thiosulfate and polythionates" @default.
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- W2951617952 doi "https://doi.org/10.1016/0076-6879(94)43037-3" @default.
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