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- W2951617972 abstract "4-Hydroxycoumarin (1) is a useful synthon in synthetic organic chemistry and a basic skeleton of several bioactive compounds. The direct functionalization of 1 with novel catalytic system would provide an efficient meaning for construction of a chemical library. Here, we developed a new catalytic system using palladium(II) acetate for the C3 regioselective mono-arylation of 1. The 3-mono-arylated and the 3,4-disubstituted coumarins were synthesized to enable derivatization. This palladium-catalyzed direct arylation of 1 is effective for rapid diversification and chemical library construction." @default.
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- W2951617972 date "2014-05-01" @default.
- W2951617972 modified "2023-10-14" @default.
- W2951617972 title "Palladium-catalyzed C3-selective mono-arylation of 4-hydroxycoumarin" @default.
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- W2951617972 doi "https://doi.org/10.1016/j.tetlet.2014.04.041" @default.
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