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- W2951619261 abstract "The samarium(II) iodide mediated reaction of N,N-dibenzyl-protected (S)-alpha-amino aldehydes with (1S,2R)-N-methylephedrinyl acrylate gave the (4R,1'S)-gamma-(aminoalkyl)-gamma-butyrolactones in good yields with high diastereoselectivities (up to 80% de); (4R,1'S)-gamma-amino-(2-phenylethyl)-gamma-butyrolactone (6a), which should be a potent precursor for gamma-secretase inhibitors, was obtained with high de value." @default.
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- W2951619261 date "2003-02-04" @default.
- W2951619261 modified "2023-10-17" @default.
- W2951619261 title "One-Step Highly Diastereoselective Synthesis of γ-Aminoalkyl-Substituted γ-Butyrolactones by an Asymmetric Samarium-Mediated Ketyl−Alkene Coupling Reaction" @default.
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- W2951619261 doi "https://doi.org/10.1021/jo020574h" @default.
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