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- W2951683849 abstract "A straightforward access to protected 8-fluoro nucleosides via metalation−electrophilic fluorination under heterogeneous reaction conditions is reported. This is the first synthesis of 8-fluoro-2‘-deoxyribonucleoside derivatives. Phenylsulfonyl substituted nucleosides are accompanying byproducts, possibly indicating a competing radical process. Higher yields of 8-fluoro derivatives were obtained with 2‘-deoxyribonucleosides, as compared to ribonucleosides. Deprotection of the hydroxyl groups leading to 8-fluoro-2‘-deoxyadenosine using TASF in methylene chloride demonstrates the compatibility of desilylation with 8-fluoro substituted nucleosides. NMR data indicate a syn conformation of the 8-fluoro derivatives." @default.
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- W2951683849 date "2007-09-29" @default.
- W2951683849 modified "2023-10-18" @default.
- W2951683849 title "Direct Synthesis of 8-Fluoro Purine Nucleosides via Metalation−Fluorination" @default.
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- W2951683849 doi "https://doi.org/10.1021/jo071121l" @default.
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