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- W2951697744 abstract "The synthesis of a new chiral oxazolidinone auxiliary based on d-xylose is described which is employed in diastereoselective Staudinger-type β-lactam syntheses. Using 2-chloro-1-methylpyridinium iodide as the dehydrating reagent, the reaction of auxiliary tethered acetic acid with acyclic or cyclic imines gave the desired β-lactams in good yields with excellent cis- or trans-selectivity depending on the geometry of the imine. X-Ray structure determination of one of the obtained compounds corroborated the absolute configuration for all cis products." @default.
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- W2951697744 date "2000-02-01" @default.
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- W2951697744 title "Synthesis of a new chiral oxazolidinone auxiliary based on d-xylose and its application to the Staudinger reaction" @default.
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- W2951697744 doi "https://doi.org/10.1016/s0957-4166(99)00506-6" @default.
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