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- W2951698629 abstract "Sequential chlorination/fluorination of aromatic trifluoroacetylated ketones gives 1-aryl 2-chloro-2,4,4,4-tetrafluorobutan-1,3-dione hydrates that are used for the synthesis of ketones and alkenes exhibiting a terminal bromochlorofluoromethyl group. The hydrates undergo detrifluoroacetylative cleavage and subsequent bromination in the presence of a copper(II) bisoxazoline catalyst, K2CO3, and NBS at room temperature. The corresponding bromochlorofluoromethyl ketones can be applied in Wittig and Horner–Wadsworth–Emmons reactions and dibromoalkenylations." @default.
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- W2951698629 date "2016-11-01" @default.
- W2951698629 modified "2023-09-27" @default.
- W2951698629 title "ChemInform Abstract: Detrifluoroacetylative Generation of Halogenated Enolates: Practical Access to Perhalogenated Ketones and Alkenes." @default.
- W2951698629 cites W2339967475 @default.
- W2951698629 doi "https://doi.org/10.1002/chin.201650035" @default.
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