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- W2951698648 abstract "A highly efficient and practical synergistically metal/proton-catalyzed Conia–ene reaction for the synthesis of bicyclo[3.n.1]alkanones has been developed. This synergistic catalysis was successfully utilized in modifying natural compounds such as methyl dihydrojasmonate, α,β-thujone, and 5α-cholestan-3-one. Furthermore, the bridged carbonyl group of bicyclo[3.2.1]alkanones could be easily attacked by nucleophiles to give the ring-opened cycloheptenone products or bicyclo[4.2.1]amide in excellent yields. These reactions provide rapid access to a diverse range of cyclic structures from simple starting materials or naturally occurring compounds." @default.
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- W2951698648 date "2015-11-19" @default.
- W2951698648 modified "2023-09-25" @default.
- W2951698648 title "ChemInform Abstract: Synergistic Catalysis: Metal/Proton-Catalyzed Cyclization of Alkynones Toward Bicyclo[3.n.1]alkanones." @default.
- W2951698648 cites W2162233130 @default.
- W2951698648 doi "https://doi.org/10.1002/chin.201549052" @default.
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