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- W2951712903 endingPage "1119" @default.
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- W2951712903 abstract "Mannosylations using the new conformationally restricted donor phenyl 2,3-di-O-benzyl-4,6-O-(di-tert-butylsilylene)-1-thio-α-d-mannopyranoside (6) have been found to be β-selective with a variety of activation conditions. The simplest activation conditions were NIS/TfOH, in which case it is proposed that the β-mannoside is formed from β-selective glycosylation of the oxocarbenium ion 25 in a B2,5 conformation." @default.
- W2951712903 created "2019-06-27" @default.
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- W2951712903 date "2014-02-06" @default.
- W2951712903 modified "2023-10-18" @default.
- W2951712903 title "β-Selective Mannosylation with a 4,6-Silylene-Tethered Thiomannosyl Donor" @default.
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- W2951712903 doi "https://doi.org/10.1021/ol403722f" @default.
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