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- W2951717992 abstract "The displacement of ClCH2CO2– from cis-[Pt(PriNH2)2(ClCH2CO2)2] and [Pt(dien)(ClCH2CO2)]+(dien = 1,5-diamino-3-azapentane) by solvent, Cl–, Br–, and SCN– has been studied in aqueous solution at 25.0 °C. The reactions are catalysed by acid by way of a pre-equilibrium protonation of the carboxylate ligand. In the absence of added acid the cationic monocarboxylato complex exhibits a normal nucleophilic discrimination power, comparable to that of the corresponding chloro complex and the nucleophile-independent pathway makes only a small contribution to the consumption of the substrate. In the uncatalysed reactions of the bis(carboxylato) complex, the nucleophile-independent pathway dominates the substitution by the weak nucleophile, Cl–, and a relatively strong nucleophile, such as SCN–, is required to make the direct substitution pathway important. The unusually large contribution from the nucleophile-independent pathway is discussed." @default.
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- W2951717992 date "1986-09-30" @default.
- W2951717992 modified "2023-09-24" @default.
- W2951717992 title "ChemInform Abstract: Kinetics of the Displacement of Chloroacetate Ion from cis-Bis(chloroacetato)bis(isopropylamine)platinum(II) and the (Chloroacetato)(1,5-diamino-3-azapentane)platinum(II) Cation" @default.
- W2951717992 cites W2077245718 @default.
- W2951717992 doi "https://doi.org/10.1002/chin.198639317" @default.
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