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- W2951721306 endingPage "583" @default.
- W2951721306 startingPage "567" @default.
- W2951721306 abstract "The author's work in the past 10 years have been reviewed, focusing on their endeavor to find more effective and versatile reagents applicable to the Mitsunobu-type reactions. The project was originally planned to provide various N-alkyl-N-allylacylamides, the substrates for the aza-Claisen rearrangement the authors have developed. The effort was rewarded by more colorful results than expected originally, introducing to the chemical community two new series of reagents, that is, azodicarboxamides, such as TMAD and DHTD, and phosphoranes, such as CMBP and CMMP. The former series mediates the Mitsunobu reaction between primary alcohols and various protonic acids (N- and C-nucleophiles) of pKa up to 12, while the later, though needed a higher temperature, mediates the reactions of both primary and secondary alcohols with protonic acids of pKa of up to 23.5. Utilizing both the aza-Claisen rearrangement and new Mitsunobu reaction, a variety of natural products including isoirridomyrmecin, alpha-skytanthine, antimycin A3b as well as various alkaloids and pheromones were synthesized in reasonable ease." @default.
- W2951721306 created "2019-06-27" @default.
- W2951721306 creator A5074198515 @default.
- W2951721306 date "2001-08-01" @default.
- W2951721306 modified "2023-10-13" @default.
- W2951721306 title "光延型反応における新試薬の開発" @default.
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- W2951721306 doi "https://doi.org/10.1248/yakushi.121.567" @default.
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