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- W2951732164 abstract "This tutorial review covers the applications of aromatic compounds such as anisole derivatives as synthetic equivalents (synthons) for 1,3-dicarbonyl compounds. The aromatic nucleus is first converted under reductive Birch conditions to the corresponding 1,4-cyclohexadiene compound which is then subjected to ozonolysis. The reductive work-up of the ozonides generates the 1,3-dicarbonyl compounds. The usefulness of this reaction sequence is demonstrated in several syntheses of complex molecules. A new access to 1,3-dicarbonyl compounds by an alternative approach utilising a cobalt-catalysed Diels–Alder reaction or a 1,4-hydrovinylation reaction to generate the needed 1,4-diene derivatives is briefly discussed." @default.
- W2951732164 created "2019-06-27" @default.
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- W2951732164 date "2010-02-16" @default.
- W2951732164 modified "2023-09-26" @default.
- W2951732164 title "ChemInform Abstract: Aromatic Compounds as Synthons for 1,3-Dicarbonyl Derivatives" @default.
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- W2951732164 doi "https://doi.org/10.1002/chin.201007228" @default.
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