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• W2951734757 abstract "A novel ruthenium-catalyzed carbon−carbon bond formation between propargylic alcohols and alkenes via the allenylidene-ene reaction has been found to afford the corresponding 2,4-disubstituted-1-hexen-5-ynes in moderate yields. The finding described here discloses a new reactivity of allenylidene complexes. As a synthetic application, intramolecular cyclization of propargylic alcohols bearing an alkene moiety has been developed to give the corresponding syn-substituted chromanes in high yields with an excellent diastereoselectivity." @default.
• W2951734757 created "2019-06-27" @default.
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• W2951734757 date "2003-04-29" @default.
• W2951734757 modified "2023-09-26" @default.
• W2951734757 title "Ruthenium-Catalyzed Carbon−Carbon Bond Formation between Propargylic Alcohols and Alkenes via the Allenylidene-Ene Reaction" @default.
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• W2951734757 doi "https://doi.org/10.1021/ja035106j" @default.
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