Matches in SemOpenAlex for { <https://semopenalex.org/work/W2951737303> ?p ?o ?g. }
- W2951737303 endingPage "3652" @default.
- W2951737303 startingPage "3643" @default.
- W2951737303 abstract "Ruthenium complexes [(η5-C5H5)Ru(κ1-P-PPh2Py)(PPh3)Cl] (1) and [(η5-C5H5)Ru(κ2-P-N-PPh2Py)(PPh3)]+ (1a) containing diphenyl-2-pyridylphosphine (PPh2Py) are reported. Coordinated PPh2Py in the complex [(η5-C5H5)Ru(κ1-P-PPh2Py)(PPh3)Cl] (1) exhibits monodentate behavior. In presence of NH4PF6 in methanol at room temperature it afforded chelated complex [(η5-C5H5)Ru(κ2-P,N-PPh2Py)(PPh3)]+ (1a). Further, 1 reacted with various species viz., CH3CN, NaCN, NH4SCN and NaN3 to afford cationic and neutral complexes [(η5-C5H5)Ru(κ1-P-PPh2Py)(PPh3)L]+ and [(η5-C5H5)Ru(κ1-P-PPh2Py)(PPh3)L] [L = CH3CN (1b); CN− (1c); N3− (1d) and SCN− (1e)] and it’s reaction with N,N-donor chelating ligands dimethylglyoxime (H2dmg) and 1,2-phenylenediamine (pda) gave cationic complexes [(η5-C5H5)Ru(κ1-P-PPh2Py)(κ2-N-N)]PF6 [κ2-N-N = dmg (1f) and pda (1g)]. The complexes 1–1g have been characterized by physicochemical techniques and crystal structures of 1, 1a, 1c, 1e and 1f have been determined by single crystal X-ray analyses. Catalytic potential of the complex 1 has been evaluated in water under aerobic conditions. It was observed that the complex 1 selectively catalyzes reduction of aldehyde into alcohol." @default.
- W2951737303 created "2019-06-27" @default.
- W2951737303 creator A5030108485 @default.
- W2951737303 creator A5034434638 @default.
- W2951737303 creator A5035021700 @default.
- W2951737303 creator A5083797035 @default.
- W2951737303 date "2009-10-01" @default.
- W2951737303 modified "2023-10-16" @default.
- W2951737303 title "Structures, preparation and catalytic activity of ruthenium cyclopentadienyl complexes based on pyridyl-phosphine ligand" @default.
- W2951737303 cites W1439705530 @default.
- W2951737303 cites W150764729 @default.
- W2951737303 cites W1594652603 @default.
- W2951737303 cites W1786162208 @default.
- W2951737303 cites W1964314803 @default.
- W2951737303 cites W1965098657 @default.
- W2951737303 cites W1971313723 @default.
- W2951737303 cites W1971685684 @default.
- W2951737303 cites W1978042060 @default.
- W2951737303 cites W1980478862 @default.
- W2951737303 cites W1980519181 @default.
- W2951737303 cites W1993939312 @default.
- W2951737303 cites W1995962029 @default.
- W2951737303 cites W2002669260 @default.
- W2951737303 cites W2010530847 @default.
- W2951737303 cites W2012013667 @default.
- W2951737303 cites W2012069603 @default.
- W2951737303 cites W2014731464 @default.
- W2951737303 cites W2014874363 @default.
- W2951737303 cites W2019467429 @default.
- W2951737303 cites W2020653096 @default.
- W2951737303 cites W2022624426 @default.
- W2951737303 cites W2023886320 @default.
- W2951737303 cites W2024172876 @default.
- W2951737303 cites W2024554544 @default.
- W2951737303 cites W2025539316 @default.
- W2951737303 cites W2031710628 @default.
- W2951737303 cites W2039948770 @default.
- W2951737303 cites W2047322882 @default.
- W2951737303 cites W2054953817 @default.
- W2951737303 cites W2066736253 @default.
- W2951737303 cites W2067263575 @default.
- W2951737303 cites W2074013990 @default.
- W2951737303 cites W2078202855 @default.
- W2951737303 cites W2079252964 @default.
- W2951737303 cites W2092616306 @default.
- W2951737303 cites W2103459003 @default.
- W2951737303 cites W2103968992 @default.
- W2951737303 cites W2115023360 @default.
- W2951737303 cites W2129213133 @default.
- W2951737303 cites W2334251112 @default.
- W2951737303 cites W2476862745 @default.
- W2951737303 cites W2950084479 @default.
- W2951737303 cites W2950344757 @default.
- W2951737303 cites W2950738829 @default.
- W2951737303 cites W2950862051 @default.
- W2951737303 cites W2951025099 @default.
- W2951737303 cites W2951114800 @default.
- W2951737303 cites W90748194 @default.
- W2951737303 doi "https://doi.org/10.1016/j.jorganchem.2009.07.011" @default.
- W2951737303 hasPublicationYear "2009" @default.
- W2951737303 type Work @default.
- W2951737303 sameAs 2951737303 @default.
- W2951737303 citedByCount "23" @default.
- W2951737303 countsByYear W29517373032012 @default.
- W2951737303 countsByYear W29517373032014 @default.
- W2951737303 countsByYear W29517373032015 @default.
- W2951737303 countsByYear W29517373032016 @default.
- W2951737303 countsByYear W29517373032017 @default.
- W2951737303 countsByYear W29517373032018 @default.
- W2951737303 countsByYear W29517373032019 @default.
- W2951737303 countsByYear W29517373032021 @default.
- W2951737303 countsByYear W29517373032023 @default.
- W2951737303 crossrefType "journal-article" @default.
- W2951737303 hasAuthorship W2951737303A5030108485 @default.
- W2951737303 hasAuthorship W2951737303A5034434638 @default.
- W2951737303 hasAuthorship W2951737303A5035021700 @default.
- W2951737303 hasAuthorship W2951737303A5083797035 @default.
- W2951737303 hasConcept C115624301 @default.
- W2951737303 hasConcept C116569031 @default.
- W2951737303 hasConcept C155647269 @default.
- W2951737303 hasConcept C161790260 @default.
- W2951737303 hasConcept C170493617 @default.
- W2951737303 hasConcept C178516000 @default.
- W2951737303 hasConcept C178790620 @default.
- W2951737303 hasConcept C179104552 @default.
- W2951737303 hasConcept C181458950 @default.
- W2951737303 hasConcept C183882617 @default.
- W2951737303 hasConcept C185592680 @default.
- W2951737303 hasConcept C188027245 @default.
- W2951737303 hasConcept C197404232 @default.
- W2951737303 hasConcept C2777716191 @default.
- W2951737303 hasConcept C2779607525 @default.
- W2951737303 hasConcept C2779825165 @default.
- W2951737303 hasConcept C55493867 @default.
- W2951737303 hasConcept C555196967 @default.
- W2951737303 hasConcept C71240020 @default.
- W2951737303 hasConcept C8010536 @default.
- W2951737303 hasConceptScore W2951737303C115624301 @default.