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- W2951762380 abstract "Abstract Hydrosilylation of 2-methyl-1-phenyl-pentan-1-one with Et3SiH in the presence of catalytic amounts of B(C6F5)3 gave the anti-product with slight predominance over syn-product (syn/anti=1:1.5). In contrast, the syn-product was obtained stereoselectively in the reaction of 2-methyl-1-phenyl-pent-4-yn-1-one bearing an ethynyl group at the β-position (syn/anti=7:1). The syn-selectivities were also observed in the B(C6F5)3-catalyzed reactions of other related ketones, such as α-methyl-β-alkynyl aryl ketones and α-methyl-β-alkynyl alkyl ketones. The moderate anti-selectivity observed in the former case can be explained by the ordinary Felkin–Anh model. On the other hand, the unusual syn-selectivity in the latter cases can be accounted for by the σ–π chelation by R3Si+, in which both the lone pair (σ) of the carbonyl group and the π-electrons of the alkyne coordinate to the silylium ion. The σ–π chelation control was also effective for the 1,3-asymmetric induction." @default.
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- W2951762380 date "2003-02-25" @default.
- W2951762380 modified "2023-09-27" @default.
- W2951762380 title "Lewis Acid Catalyzed Stereoselective Hydrosilylation of Ketones under the Control of σ—π Chelation." @default.
- W2951762380 cites W2084582848 @default.
- W2951762380 doi "https://doi.org/10.1002/chin.200308056" @default.
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