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- W2951765075 abstract "An efficient diastereo- and enantioselective access to all-syn-configured, differently N,O-protected 1,3-amino alcohols via a titanium tetrachloride mediated aza-enolate aldol reaction/aldehyde hydrazone 1,2-addition protocol is described. The O-TBS and N-Cbz protected title compounds are obtained after reductive N-N bond cleavage in a four steps synthesis with moderate to good overall yields (18-58%), high diastereomeric (de = 78% to ÷96%) and enantiomeric (ee ÷96%) excesses." @default.
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- W2951765075 date "2004-07-13" @default.
- W2951765075 modified "2023-09-23" @default.
- W2951765075 title "Diastereo- and Enantioselective Synthesis of Differently <i>N</i>,<i>O</i>-Protected 1,3-Amino Alcohols with Three Neighbouring Stereogenic Centers" @default.
- W2951765075 doi "https://doi.org/10.1055/s-2004-829142" @default.
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