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• W2951765862 abstract "Radical adducts of S-α-ketonyl dithiocarbonates (xanthates) to triethyl vinylsilane are converted into triethylsilyl-substituted cyclopropanes upon ozonolysis followed by exposure to 1,4-dibromobutane and Cs2CO3/18-crown-6 in refluxing acetonitrile. The sequence works best with phenacyl type adducts, and the use of the less bulky trimethysilyl (TMS) derivatives results in extensive desilylation." @default.
• W2951765862 created "2019-06-27" @default.
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• W2951765862 date "2014-11-21" @default.
• W2951765862 modified "2023-09-25" @default.
• W2951765862 title "Novel Route to Triethylsilyl-Substituted Cyclopropanes" @default.
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• W2951765862 doi "https://doi.org/10.1021/ol503081b" @default.
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