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• W2951767132 abstract "The potential of halogen-magnesium exchange reactions, followed by quenching with electrophiles, for the functionalization of the pyridazin-3(2H)-one core was investigated. 2-Benzyl-4-bromo-5-methoxy- (1), 2-benzyl-5-bromo-4-methoxy- (4), and 2-benzyl-4,5-dibromopyridazin-3(2H)-one (10) were selected as readily available model substrates. While 1 and 10 gave exclusively C-4 metalation, a tandem reaction involving nucleophilic substitution via addition elimination and bromine-magnesium exchange was observed with 4." @default.
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• W2951767132 date "2009-11-20" @default.
• W2951767132 modified "2023-09-27" @default.
• W2951767132 title "Synthesis of Functionalized Pyridazin-3(2<i>H</i>)-ones via Bromine−Magnesium Exchange on Bromopyridazin-3(2<i>H</i>)-ones" @default.
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• W2951767132 doi "https://doi.org/10.1021/jo9020985" @default.
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