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- W2951770101 abstract "The kinetics and the mechanism of the ligand substitution reaction between ethylenediaminetetraacetatocuprate-(II)(CuY2−) and triethylenetetraminezinc(II)(ZnT2+) were studied spectrophotometrically in the pH range 7.0–10.5 at I=0.2(NaClO4) and 25.0 °C. The exchange reaction was accelerated by traces of either EDTA or triethylenetetramine(Trien). The exchange reaction was shown to proceed by the chain reaction mechanism where the chain-propagating steps are the reaction of CuY2− with Trien and the reaction of ZnT2+ with EDTA. Each chain-propagating step was investigated. The apparent rate constant of the reaction of CuY2− with Trien increases with pH, while that of ZnT2+ with EDTA decreases with pH." @default.
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- W2951770101 date "1976-03-16" @default.
- W2951770101 modified "2023-09-26" @default.
- W2951770101 title "ChemInform Abstract: MULTIDENTATE LIGAND KINETICS. I. THE LIGAND SUBSTITUTION REACTION BETWEEN ETHYLENEDIAMINETETRAACETATOCUPRATE(II) AND TRIETHYLENETETRAMINEZINC(II)" @default.
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- W2951770101 doi "https://doi.org/10.1002/chin.197611350" @default.
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