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- W2951773296 abstract "tert-Pentyl groups are recognized to be highly effective steric groups that can enhance enantioselectivity of salen titanium complexes when they are used in asymmetrical cyanation of aromatic aldehydes. High ee (92-97%) has been obtained with several aldehyde substrates. Compared to its tert-butyl analogue, the tert-pentyl group has been found to improve enantioselectivity and in some cases quite dramatically." @default.
- W2951773296 created "2019-06-27" @default.
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- W2951773296 date "2010-05-19" @default.
- W2951773296 modified "2023-09-26" @default.
- W2951773296 title "ChemInform Abstract: Tertiary Pentyl Groups Enhance Salen Titanium Catalyst for Highly Enantioselective Trimethylsilylcyanation of Aldehydes." @default.
- W2951773296 cites W2178284813 @default.
- W2951773296 doi "https://doi.org/10.1002/chin.200239087" @default.
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